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Synthesis of monodispersed palladium nanoparticle at room temperature and its catalytic activity for Suzuki-Miyaura cross-coupling reaction

By: Roy, Subhasish.
Contributor(s): Senapati, Kula Kamal.
Publisher: New Delhi CSIR 2022Edition: Vol.61, Jan.Description: 99-105p.Subject(s): GENERAL CHEMISTRYOnline resources: Click here In: Indian journal of chemistry (Section B)Summary: A new method has been developed for the synthesis of spherical palladium nanoparticles with narrow size distribution. Pd nanoparticles of average particle size of around 7 nm have been prepared from Pd(OAc)2 at room temperature in THF using 2-(trimethyl silyl)-ethanol (TMSE) as a reducing as well as capping agent. The catalytic activity of the Pd-nanoparticles has been examined for ligand free Suzuki-Miyaura cross-coupling reaction.
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A new method has been developed for the synthesis of spherical palladium nanoparticles with narrow size distribution. Pd nanoparticles of average particle size of around 7 nm have been prepared from Pd(OAc)2 at room temperature in THF using 2-(trimethyl silyl)-ethanol (TMSE) as a reducing as well as capping agent. The catalytic activity of the Pd-nanoparticles has been examined for ligand free Suzuki-Miyaura cross-coupling reaction.

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